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Abstract Particle density effects in heterogeneous catalysis are elusive because particle density usually changes simultaneously with particle size. Here we show that the size and shape of Ru particles, formed by reducing epitaxial rutile-RuO2 structures supported on rutile TiO2 with closely matched lattices, remain constant with 16-fold change in density.
Abstract Click to copy section linkSection link copied! Hydrocracking is a promising route for the chemical recycling of polyolefins (PO), converting them into short hydrocarbons over bifunctional catalysts with metal sites for hydrogenation and dehydrogenation, and Brønsted acid sites (BAS) for isomerization and C–C bond cleavage.
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