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Orbital analysis of bonding in diarylhalonium salts and relevance to periodic trends in structure and reactivity† Shubhendu S. Karandikar,a Avik Bhattacharjee,a Bryan E. Metze,a Nicole Javaly, a Edward J. Valente,*b Theresa M. McCormick*a and David R. Stuart *a Abstract Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field of organic synthesis.
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