Molten metal closo-borate solvates Solvated lithium closo-dodecaborate, Li2B12H12 with tetrahydrofuran and acetonitrile, show unexpected melting at < 150 °C. This feature has been explored to melt-infiltrate Li2B12H12 in a nanoporous SiO2 scaffold. The ionic conductivity of Li2B12H12·xACN reaches 0.08 mS cm-1 in the liquid state at 150 °C making them suitable as battery electrolytes. You have access to this article Please wait while we load your content... Something went wrong. Try again?