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Noah A. Grinde

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Articles by Noah A. Grinde

Nonlinear Optical Properties of Mechanically Interlocked Nanohoops

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By Juan Sandoval, Yuqiu Lei, Bishal Saha, Noah A. Grinde
| ACS Publications
Abstract Click to copy section linkSection link copied! The design of molecular systems that harness spatial topology to modulate light–matter interactions is a powerful and emerging approach in modern photonics, opening up new possibilities for advanced technologies. In this study, we present the first comprehensive theoretical and experimental investigation of the nonlinear optical (NLO) properties of nanohoop catenanes, which are mechanically interlocked molecular architectures.
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Cover Feature: Rapid Access to Encapsulated Molecular Rotors via Coordination‐Driven Macrocycle Formation (Chem. Eur. J. 50/2023)

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By Noah A. Grinde, Zachary R. Kehoe, Lucas J. Mancheski, Herh G. Vang
| Wiley Online Library Verified
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Rapid Access to Encapsulated Molecular Rotors via Coordination‐Driven Macrocycle Formation

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By Noah A. Grinde, Zachary R. Kehoe, Lucas J. Mancheski, Eric Bosch
| Wiley Online Library Verified
Abstract Macrocycle formation that relies upon trans metal coordination of appropriately placed pyridine ligands within an arylene ethynylene construct provides rapid and reliable access to molecular rotors encapsulated within the macrocyclic framework. Showing no significant close contacts to the central rotors, X-ray crystallography of Ag(I)-coordinated macrocycles provides plausibility for free rotation or wobbling of rotors within the central cavity.
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