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Closed-to-open-shell ground state photoswitching of thienyl-based acylhydrazones† Photoswitches convert a photon to molecular information through a reversible change in bonding or configuration. Applications of photoswitches are determined by their different properties in the two states, spanning from catalysis, to allosteric activation, to photopharmacology, up to materials and devices such as memories that can store optical information in chemical bonds.
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