A trilayer composed by an intercalated Gr/Co/Ir(111) ultra-thin structure (Fig. 1a) coupled to a Fe overlayer (Fig. 1b) displays a remarkable AFC at room temperature, as revealed by the sign switching of the Fe element-sensitive X-ray magnetic circular dichroism (XMCD) signal with and without an applied magnetic field observed in Fig. 1e, f, respectively (see Methods for further details). As deduced from the room-temperature field-dependent XMCD intensities reported in Fig.