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1 Introduction Spinel compounds of the LiNixMn2−xO4 (LNMO) family have been investigated extensively as cathode materials because of their ability to cycle at high voltages, their low cost, and their earth-abundant constituents.[1-8] These cathodes have an operating voltage of ≈4.7 V versus Li/Li+, can deliver an energy density of ≈650 Wh kg−1, possess high rate capability, and exhibit better thermal stability compared to the well-known α-NaFeO2-type layered oxide cathodes.[9-14] However,...
1. Introduction The high-voltage 5 V spinel cathode LiNi0.5Mn1.5O4 (LNMO) has an average working voltage of 4.6–4.7 V vs. Li, a high energy density of 650 Wh/kg at the material level, and a high rate performance with faster Li+ diffusion, and it is viewed as a promising cathode material for next-generation high-energy cobalt-free lithium-ion batteries [1,2,3]. However, the working voltage plateau above 4.7 V vs.
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