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Articles by Peter Sirsch
Gallatabenzene Ligands Emerging from Open Lutetocene and Yttrocene Methyl Complexes
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A Terminal Yttrium Phosphinidene
A Terminal Yttrium Phosphinidene | Journal of the American Chemical Society
A Terminal Yttrium Phosphinidene
Terminal, nondirectional ionic “multiple” bond interactions between group 15 elements and rare-earth metals (Ln) have remained a challenging target until present. Although reports on terminal imide species have accumulated in the meantime, examples of terminal congeners with the higher homologue phosphorus are yet elusive.
Open-Shell Early Lanthanide Terminal Imides
Group 3- and 4f-element organometallic chemistry and reactivity are decisively driven by the rare-earth-metal/lanthanide (Ln) ion size and associated electronegativity/ionicity/Lewis acidity criteria. For these reasons, the synthesis of terminal “unsupported” imides [Ln═NR] of the smaller, closed-shell Sc(III), Lu(III), Y(III), and increasingly covalent Ce(IV) has involved distinct reaction protocols while derivatives of the “early” large Ln(III) have remained elusive.
Angewandte Chemie International Edition
Communication Gallium Methylene Reiner Anwander Corresponding Author E-mail address: reiner.anwander@uni-tuebingen.de Universität Tübingen, Institut für Anorganische Chemie, Auf der Morgenstelle 18, 72076 Tübingen, GERMANY Search for more papers by this author PDF PDF Share Abstract Despite the eminent importance of metal alkylidene species for organic synthesis and industrial catalytic processes, molecular homoleptic metal methylene compounds [M(CH2)n] as the simplest representatives, have...
Angewandte Chemie International Edition
Communication Gallium Methylene Reiner Anwander Corresponding Author E-mail address: reiner.anwander@uni-tuebingen.de Universität Tübingen, Institut für Anorganische Chemie, Auf der Morgenstelle 18, 72076 Tübingen, GERMANY Search for more papers by this author PDF PDF Share Abstract Despite the eminent importance of metal alkylidene species for organic synthesis and industrial catalytic processes, molecular homoleptic metal methylene compounds [M(CH2)n] as the simplest representatives, have...
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