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The preparation and properties of the complex (R ,R)-MoTp(NO)(DMAP)(?2-?-pinene) are described (?10 g scale; DMAP = 4-(dimethylamino)pyridine; Tp = hydridotris(pyrazolyl)borate). This complex undergoes exchange of the pinene with a wide range of other ? ligands including acetone, ethyl acetate, N,N-dimethylformamide, acetonitrile, and naphthalene.
The large-scale synthesis of the scorpionate ligand Ttz (hydrotris(1,2,4-triazol-1-yl)borate) is reported as well as syntheses of Group VI complexes K[M(L)(CO) ] and M(L)(NO)(CO) (L = Ttz or Tp (hydrotris(pyrazol-1-yl)borate), M = Mo or W). The redox characteristics of the metal in these Ttz complexes are shown to be reversibly modulated by interactions between the exo-4-N lone pairs of the triazolyl rings and Brønsted or Lewis acids.
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