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The hydrogenation of levulinic acid (LA) to -valerolactone (GVL) was studied by using mono- and bidentate p-cymene ruthenium(II) N-heterocyclic carbene (NHC) complexes as catalysts precursors. In water, all complexes were found to be reduced in-situ to form ruthenium nanoparticles (RuNPs) with a high hydrogenation activity.
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