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1 Introduction Rechargeable aqueous Zn-ion batteries (AZIBs) are considered promising candidates for grid-scale energy storage, owing to the intrinsic merits of Zn metal anodes [1-4], including a high theoretical specific capacity (820 mA h g−1), relatively low redox potential (−0.762 V vs. the standard hydrogen electrode (SHE)), low cost ($1.45 per lb), good stability toward aqueous electrolytes and environmental friendliness [5, 6].
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