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In addition to their optoelectronic applications, Zn-based oxides and sulfides have also been widely studied as materials for use as electrodes in Li-ion batteries owing to their high theoretical capacity. However, both the materials suffer from a drastic loss in capacity due to their poor conductivity and electrochemical instability. A very efficient and carefully controlled combination may address these limitations.
We report a novel P2-type Na0.5Ni0.26Cu0.07Mn0.67O2 (NCM) mixed oxide obtained by conventional solid-state method as prospective cathode for sodium-ion battery (SIB) applications. X-ray diffraction analysis shows that NCM exhibits a hexagonal structure with a P63/mmc (No. 194) space group, in which Na-ions are located in a prismatic environment.
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