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Abstract We investigate La-site bonding by La N\(_{4,5}\)-edge RIXS together with structural parameters and the superconducting transition temperature \(T_c\) of optimally doped La\(_{1.84}\)M\(_{0.16}\)CuO\(_4\) (M = Ca, Sr, Ba) epitaxial films and the La\(_2\)CuO\(_4\) host lattice. La and M in the A-site have been considered to be part of the axial hybrid state formed by Cu 4s, apical O 2\(p_z\), and rare earth (La) states.
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