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Articles by Ryan A. Hackler
Ethylene polymerization with a crystallographically well-defined metal-organic framework supported catalyst
Ethylene polymerization with a crystallographically well-defined metal–organic framework supported catalyst† Timothy A. Goetjen, ab Julia G. Knapp, a Zoha H. Syed, ab Ryan A. Hackler, b Xuan Zhang, a Massimiliano Delferro, b Joseph T. Hupp *a and Omar K.
Isomerization and Selective Hydrogenation of Propyne: Screening of Metal-Organic Frameworks Modified by Atomic Layer Deposition
Various metal oxide clusters upward of 8 atoms (Cu, Cd, Co, Fe, Ga, Mn, Mo, Ni, Sn, W, Zn, In, and Al) were incorporated into the pores of the metal–organic framework (MOF) NU-1000 via atomic layer deposition (ALD) and tested via high-throughput screening for catalytic isomerization and selective hydrogenation of propyne.
Upcycling Single-Use Polyethylene into High-Quality Liquid Products
Synopsis Single-use polyethylene is converted into value-added high-quality liquid products by a catalytic upcycling process using platinum nanoparticles supported on perovskites. Polyolefins are ubiquitous in single-use and short-term applications because their starting materials are abundant and inexpensive.
Expanding applications of SERS through versatile nanomaterials engineering
Surface-enhanced Raman scattering (SERS) spectroscopy has evolved into a cross-disciplinary analytical technique by unveiling relevant chemical, biological, material, and structural information. The focus of this review is on two critical properties for successfully expanding applications of SERS spectroscopy: quality of the plasmonic substrate and molecule localization to the substrate.
Identification of Dimeric Methylalumina Surface Species during Atomic Layer Deposition Using Operando Surface-Enhanced Raman Spectroscopy
Operando surface-enhanced Raman spectroscopy (SERS) was used to successfully identify hitherto unknown dimeric methylalumina surface species during atomic layer deposition (ALD) on a silver surface. Vibrational modes associated with the bridging moieties of both trimethylaluminum (TMA) and dimethylaluminum chloride (DMACl) surface species were found during ALD. The appropriate monomer vibrational modes were found to be absent as a result of the selective nature of SERS.
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