1 Introduction The interaction between the perovskite ink and the underlying charge transport layer (CTL) coated substrate strongly determines 1) the uniformity and crystallization of lead halide perovskite thin-films, 2) their charge transport properties,[1-5] 3) radiative and non-radiative recombination processes,[3, 6, 7] 4) reproducibility in the device performance over a large area and 5) the stability.[8-10] The solvents that are used for perovskite ink processing, such as N-N′-dimethyl...