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Articles by Samuel G. Shepard
Assessing the United States’ most frequently asked questions about osteopathic medicine, osteopathic education, and osteopathic manipulative treatment
Abstract Context Osteopathic medicine in the United States continues to produce a substantial number of physicians and medical educators. However, recently popularized misconceptions about osteopathic medical practice, education, and manual therapy suggest an unsettling prevalence of inaccurate beliefs held by the public.
An analysis of publication trends of orthopedic surgery residency graduates in relation to academic achievement
Research experiences, such as written abstracts, conference presentations, and peer-reviewed publications, are considered key benchmarks of a medical student’s residency application [1, 2]. Residency program directors may utilize objective measures to compare one applicant to the next, and previous literature has shown that program directors view research as an important component of one’s application and may increase the likelihood of successful matching into competitive programs [3].
Are randomized controlled trials in urology being conducted with justification?
Abstract Context: Considering the substantial increase in research funding in the field of urology, minimizing research waste should be a top priority. Systematic reviews (SRs) compile available evidence regarding a clinical question into a single critical resource. If properly utilized, SRs can help minimize redundant studies, focus attention to unsubstantiated treatments, and reduce research waste.
A Synthetically Tunable System To Control MLCT Excited-State Lifetimes and Spin States in Iron(II) Polypyridines
2,2?:6?,2?-Terpyridyl (tpy) ligands modified by fluorine (dftpy), chlorine (dctpy), or bromine (dbtpy) substitution at the 6- and 6?-positions are used to synthesize a series of bis-homoleptic Fe(II) complexes. Two of these species, [Fe(dctpy) ]2+ and [Fe(dbtpy) ]2+, which incorporate the larger dctpy and dbtpy ligands, assume a high-spin quintet ground state due to substituent-induced intramolecular strain.
Uncovering the Roles of Oxygen in Cr(III) Photoredox Catalysis
A combined experimental and theoretical investigation aims to elucidate the necessary roles of oxygen in photoredox catalysis of radical cation based Diels–Alder cycloadditions mediated by the first-row transition metal complex [Cr(Ph phen) ]3+, where Ph phen = bathophenanthroline. We employ a diverse array of techniques, including catalysis screening, electrochemistry, time-resolved spectroscopy, and computational analyses of reaction thermodynamics.
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