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Gold carbonyl cations and beyond: homoleptic gold(i) complexes with P4 and P4S3 and the half-sandwich cation [Au(C6H6)(CO)]+† Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the perfluoroalkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry.
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