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Editor’s summary The light-induced decomposition of ferrioxalate salts to produce carbon dioxide and reduced iron is so well studied that it is widely used as a standard to determine the efficiency of other photochemical reactions. Bernabeu et al. nonetheless found a way to take this reaction in a different direction, using it as a means rather than an end.
Research Article Dedicated to Professor Enrique Ortí on the occasion of his 65th birthday Graphical Abstract The self-assembly of N-annulated perylene bisimides (N-PBIs) has demonstrated that the ability of these units to generate different polymorphs upon supramolecular polymerization decreases as the length of the alkyl bridge separating the peripheral side chains and the central aromatic backbones decreases.
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