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Articles by Shuxuan Tang
A persistent germylyne radical enabling reversible σ-dimerization and diverse bond activation
Abstract The reversible σ-dimerization of radicals is a fundamental process in bond formation and cleavage, yet achieving this with an isolable heavy carbyne analogue has remained a paramount challenge. Herein, we report the synthesis and characterization of an isolable germylyne radical that demonstrates remarkable ambient stability while undergoing clean, reversible σ-dimerization via a Ge–Ge single bond.
Rational Design of Crystalline and Enantiomerically Pure Helicenes with Open‐Shell Singlet Ground States
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Urine Proteomics in Methamphetamine Addicted Patients
Abstract Drug addiction is a serious chronic relapsing brain disease, and methamphetamine dependence has a complex course and is difficult to treat, causing a serious public health burden. In this study, we compared and analyzed the urine proteome of methamphetamine-using patients, methamphetamine-withdrawing patients, healthy individuals.
Spin Frustration in Organic Radicals
Conflict of interest The authors declare no conflict of interest. References 1, Phys. Rev. 1950, 79, 357–364. 2, Phys. Rev. 1956, 102, 1008–1013. 3, Mater. Res. Bull. 1973, 8, 153–160. 4, Annu. Rev. Mater. Sci. 1994, 24, 453–480. 5, Ann. Phys. 1999, 511, 191–254. 6, J. Mater. Chem. 2001, 11, 37–53. 7, , Phys. Today 2006, 59, 24–29. 8, , , Int. J. Quantum Chem. 2007, 107, 3219–3227. 9, , , , Phys. Rev. B 2008, 78, 144404. 10, , , , , , , , , AIP Conf. Proc. 2009, 1108, 20–29. 11, , , , , , , , , , J. Phys. Chem.
Spin Frustration in Organic Radicals
Spin frustration, resulted from geometric frustration and a systematical inability to satisfy all antiferromagnetic (AF) interactions between the unpaired spins simultaneously, is under spotlight for its importance in physics and materials science. Spin frustration is treated as structural basis of quantum spin liquid (QSL). Featuring flexible chemical structures, organic radical species exhibit great potential in building spin-frustrated molecules and lattices.
A Triply Negatively Charged Nanographene Bilayer with Spin Frustration
Graphical Abstract A triply negatively charged radical species based on a bilayer of a C96 nanographene was synthesized and characterized. It is stabilized as an open-shell doublet ground state with an excited quartet state. It is the largest well-defined open-shell graphenic bilayer and also the first example of a triply negatively charged radical π-dimer. Spin frustration is observed in this species.
Urinary Proteome Changes during Pregnancy in Rats
Abstract : Pregnancy involves a significant number of physiological changes. A normal pregnancy is essential to ensure healthy maternal and fetal development. We sought to explore whether the urinary proteome could reflect the pregnancy process. Urine samples were collected from pregnant and control rats on various gestational days.
Recent advances in stable main group element radicals: preparation and characterization
Recent advances in stable main group element radicals: preparation and characterization Zhongtao Feng,a Shuxuan Tang,a Yuanting Su b and Xinping Wang *a Abstract Radical species are significant in modern chemistry. Their unique chemical bonding and novel physicochemical properties play significant roles not only in fundamental chemistry, but also in materials science. Main group element radicals are usually transient due to their high reactivity.
A cationic sulfur-hydrocarbon triradical with an excited quartet state
A cationic sulfur-hydrocarbon triradical with an excited quartet state† The triptycene-bridged tris(thianthrene) compound 1 was designed and synthesized. Three-electron oxidation of 1 by NO[Al(OC(CF3)3)4], followed by crystallization at two different temperatures resulted in the triradical trication salts 2a and 2b respectively, which feature different crystal packing patterns.
A stable triplet diradical emitter
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A Magnetically Robust Triplet Ground State Sulfur-Hydrocarbon Diradical Dication
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Tunable Reduction of 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐Triazine: from Radical Anion to Diradical Dianion to Radical‐Contained Metal‐Organic Framework
Communication Tunable Reduction of 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐Triazine: from Radical Anion to Diradical Dianion to Radical‐Contained Metal‐Organic Framework Xinping Wang Corresponding Author E-mail address: xpwang@nju.edu.cn Nanjing University, Chemistry, Xianlin Ave 163, 210023 Nanjing, CHINA Search for more papers by this author PDF PDF Share Abstract The reduction of 2,4,6‐tri(4‐pyridyl)‐1,3,5‐triazine (TPT) with alkali metals resulted in the radical anion salts ( 1 , 2 , 4 and 5 ) and...
Tricoordinate Nontrigonal Pnictogen‐Centered Radical Anions: Isolation, Characterization and Reactivity - Mondal - - Angewandte Chemie International Edition - Wiley Online Library
Communication Tricoordinate Nontrigonal Pnictogen‐Centered Radical Anions: Isolation, Characterization and Reactivity Xinping Wang Corresponding Author E-mail address: xpwang@nju.edu.cn Nanjing University, Chemistry, Xianlin Ave 163, 210023 Nanjing, CHINA Search for more papers by this author PDF PDF Share Abstract The search for main‐group element‐based radicals is one of the main research topics in contemporary chemistry because of their fascinating chemical and physical properties.
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