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Abstract Engineering vacancy interfaces in semiconductor–metal-organic framework heterostructures provides a promising route to regulate interfacial charge transfer under solar irradiation. Here, we construct a near-infrared-active Nd–BiO2-x/MIL-101(Fe) heterostructure, where ultrathin oxygen-vacancy-rich Nd-doped BiO2-x nanosheets (2-5 nm) are anchored onto porous MIL-101(Fe) through Bi–O = C bonds.
The critical need for lunar in situ resource utilization (ISRU) to enable long-term lunar habitation provides a compelling context in chemistry education. This paper introduces “Simulating the Construction of a Lunar Base”, a Project-Based Learning (PBL) module for high school chemistry. Students, acting as “Lunar Engineers and Geochemists”, apply core chemical principles to the design and construction of a lunar base.
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