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The novel photoactive ruthenium( ) complex cis-[Ru(bpy) (INH) ][PF ] (1·2PF , INH = isoniazid) was designed to incorporate the anti-tuberculosis drug, isoniazid, that could be released from the Ru( ) cage by photoactivation with visible light. In aqueous solution, 1 rapidly released two equivalents of isoniazid and formed the photoproduct cis-[Ru(bpy) (H O) ] upon irradiation with 465 nm blue light.
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