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Copper(i)-catalyzed click chemistry in deep eutectic solvent for the syntheses of β-d-glucopyranosyltriazoles† Subrat Sethi,a Narayan Ch. Jana, a Surajit Panda, a Suraj Kumar Maharanaa and Bidraha Bagh *a Abstract In the last two decades, click chemistry has progressed as a powerful tool in joining two different molecular units to generate fascinating structures with a widespread application in various branch of sciences.
In recent years, catalysis with base metal manganese has received a significant amount of interest. Catalysis with manganese complexes having N-heterocyclic carbenes (NHCs) is relatively underdeveloped in comparison to the extensively investigated manganese catalysts possessing pincer ligands (particularly phosphine-based ligands). Herein, we describe the synthesis of two imidazolium salts decorated with picolyl arms (L1 and L2) as NHC precursors.
Aerobic Oxidation of Vanillyl Alcohol to Vanillin Catalyzed by Air-Stable and Recyclable Copper Complex and TEPMO under Base-Free Conditions The need of sustainable development in modern era has driven the transformation of biomass for the production of fine chemicals into a strong trend of research. The aerobic oxidation of lignin derived monomeric phenolics for the synthesis of various value added products has attracted significant attention of the scientific community.
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