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1 Introduction Metalloenzymes activate small molecules, such as dioxygen and hydrogen peroxide, with remarkable selectivity under physiological conditions [1, 2]. In biological systems, first-row transition metals—particularly iron, copper, and manganese—serve as the redox-active centers that drive these oxidative transformations [3-5].
Conflicts of Interest The authors declare no conflicts of interest. Data Availability Statement The data that support the findings of this study are available on request from the corresponding author. The data are not publicly available due to privacy or ethical restrictions. Supporting Information Filename Description anie75304-sup-0001-SuppMat.pdf4.1 MB The authors have cited additional references within the Supporting Information [66-81].Supporting File: anie75304-sup-0001-SuppMat.pdf.
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