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Anionic Guest-Dependent Slow Magnetic Relaxation in a Co(II) Tripodal Iminopyridine Complex We report the syntheses and magnetic property characterizations of four mononuclear cobalt(II) complex salts featuring a tripodal iminopyridine ligand with external anion receptor groups, [CoL5-ONHtBu]X2 (X = Cl (1), Br (2), I (3) and ClO4 (4)).
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Four new quasi-1D Ni -lantern chain complexes of the form [Ni (SOCR) (L)] (R = Ph, L = DABCO (1); R = Ph, L = pyz (2); R = CH , L = DABCO (3); R = CH , L = pyz (4)) were prepared from the reaction of [Ni (SOCR) (EtOH)], R = CH or Ph, with the N,N?-donor bridging ligands pyrazine (pyz) or 1,4-diazabicyclo[2.2.2]octane (DABCO).
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