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Preheat oven to 350°. Butter and flour an 8x8" baking dish, shaking out excess flour. Toast walnuts, if using, on a rimmed baking sheet, tossing occasionally, until golden brown, 8–10 minutes; let cool. Increase oven temperature to 375°. Whisk cocoa, salt, baking powder, and 1 cup flour in a medium bowl to combine and work out any lumps.
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