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Nucleophilic substitution results in inversion of configuration at the electrophilic carbon center (S 2) or racemization (S 1). The stereochemistry of the nucleophile is rarely considered, but phosphines, which have a high barrier to pyramidal inversion, attack electrophiles with retention of configuration at P.
Nucleophilic substitution results in inversion of configuration at the electrophilic carbon center (S 2) or racemization (S 1). The stereochemistry of the nucleophile is rarely considered, but phosphines, which have a high barrier to pyramidal inversion, attack electrophiles with retention of configuration at P.
Nucleophilic substitution results in inversion of configuration at the electrophilic carbon (SN2) or racemization (SN1). Stereochemistry at the nucleophile is rarely considered, but phosphines, which have a high barrier to pyramidal inversion, attack electrophiles with retention of configuration at P.
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