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Photoelectrochemical Nickel-Catalyzed Carboacylation/ Silanoylation of Alkenes with Unactivated C/Si–H Bonds Direct and selective installation of two different functional groups into the unsaturated bonds of alkenes constitutes a long-standing goal in organic synthesis. Herein, we first report a photoelectrochemical approach to the carboacylation/ silanoylation of alkenes with unactivated alkanes/hydrosilanes via the LMCT process.
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