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A series of novel boat-shaped host-guest complexes were designed and synthesized by the combination of a new calixarene fragments-based tetraphosphine ligand L with group 11 metal salts Cu(MeCN)4ClO4, AgNO3 in self-assembly process, and by the following anion exchange reactions of complex 1 with sodium p-toluenesulfonate, AcONa, PhCO2Na and sodium 9-anthrylcarboxylate.
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