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1 Introduction To address the polysulfide shuttle issue in lithium–sulfur batteries, the Manthiram group pioneered an interlayer strategy in 2012, which involves inserting a functional interlayer between the sulfur cathode and the separator to impede the migration of soluble lithium polysulfides (LiPS). This paradigm shifts the research emphasis from “closed” cathode engineering toward “open” architectural design [1].
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