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1 Introduction Near-infrared (NIR) luminescent materials play a vital role in cutting-edge technologies such as night-vision imaging, biomedical sensing, optical communication, and information security [1-3]. However, practical implementation faces a severe performance trade-off. Most current systems emit within the 700–800 nm range. This fails to effectively cover the 800–1000 nm optical window, which offers deeper penetration and lower scattering [4].
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