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1 Introduction The penostatins are a family of natural products (Figure 1) mainly found in several endophytic fungal strains including Penicillium sp. of the marine green alga Enteromorpha intestinalis [1-3], the entomogenous fungus Isaria tenuipes [4], and Penicillium sp. CPCC 401423 cultured on rice [5]. Numata group investigated the cytotoxic activity of the penostatins A–I using P388 lymphocytic leukaemia tumor cell lines.
1 Introduction The penostatins are a family of natural products (Figure 1) mainly found in several endophytic fungal strains including Penicillium sp. of the marine green alga Enteromorpha intestinalis [1-3], the entomogenous fungus Isaria tenuipes [4], and Penicillium sp. CPCC 401423 cultured on rice [5]. Numata group investigated the cytotoxic activity of the penostatins A–I using P388 lymphocytic leukaemia tumor cell lines.
Asymmetric synthesis of penostatins A-D from L-ascorbic acid The first asymmetric synthesis of (-)-penostatins B and D, as well as practical synthesis of (+)-penostatins A and C have been accomplished by a flexible strategy.
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