Abdelati Naghim

1 Introduction Atropisomers are of utmost interest due to their prevalence in natural products,1 but also for their biological relevance2 and their numerous applications as chiral materials,3 ligands4 and organocatalysts.5 Among them, biaryl and heterobiaryl atropisomers are the most common, and many synthetic approaches are available (Scheme 1a).6 Non-biaryl atropisomers constitutes another family of these axially chiral molecules with fewer synthetic approaches and consequently are less...