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Abstract Propane dehydrogenation is an energy-intensive industrial reaction that requires high temperatures (550–750 °C) to overcome thermodynamic barriers. Here we overcome these limits and demonstrate that near-ambient propane dehydrogenation can be achieved through photo-thermo-catalysis in a water-vapour environment. We reduce the reaction temperature to 50–80 °C using a single-atom catalyst of copper supported on TiO2 and a continuous-flow fixed-bed reactor.
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