Ambar Banerjee
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Berry pseudorotation enabled photodissociation of Fe(CO) 5 observed by ultrafast electron diffraction
Abstract The structural dynamics of metal carbonyls are central to processes ranging from catalysis to organometallic synthesis. Here we investigate the photodissociation of a prototypical transition metal carbonyl, Fe(CO)5, using mega-electron-volt ultrafast electron diffraction.
Time-Resolved Resonant Inelastic X-ray Scattering Reveals How Orbital Symmetry Alignment Enables C–H Activation Click to copy article link Article link copied!
Introduction Click to copy section linkSection link copied! Being able to selectively activate and transform a C–H bond, one of the most ubiquitous albeit inert bonds in nature, has been a long-standing goal of organic and metal–organic chemistry. C–H functionalization in alkanes, in particular, opens the door to streamlined synthesis without the need for prefunctionalized starting materials and multistep syntheses.
Accidental Triplet Harvesting in Donor-acceptor dyads with Low Spin-orbit Coupling
Accidental Triplet Harvesting in Donor-acceptor dyads with Low Spin-orbit Coupling We present an accidental mechanism for efficient intersystem crossing (ISC) between singlet and triplet states with low spin-orbit coupling (SOC) in molecules having donor-acceptor (D-A) moieties separated by a sigma bond.
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