Amina Leoni Moshtaha on Muck Rack

Amina Leoni Moshtaha

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Articles

A decacationic ferrocene-based metallostar

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By Susanne Margot Rupf, Freie Universität Berlin, Amina Leoni Moshtaha, Moritz Malischewski
| Royal Society of Chemistry
A decacationic ferrocene-based metallostar† Susanne Margot Rupf, a Amina Leoni Moshtaha a and Moritz Malischewski *a Abstract Decacationic metallostars have been prepared by the reaction of permercurated ferrocene FeC10(HgO2CCF3)10 with superacidic (C5F5NH)(SbF6) (pKa = −11 estimated in H2O) in multigram scale. In the resulting compound, [FeC10Hg10(NC5F5)n][SbF6]10, the labile pentafluoropyridine ligands are readily displaced by acetonitrile (MeCN) or tetrahydrothiophene (THT).
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