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Convenient Access to Trisubstituted Cubanes and Nitrated Derivatives Click to copy article link Article link copied!
Abstract Click to copy section linkSection link copied! A simple laboratory-scale multigram procedure for convenient access to 1,2,4-trisubstituted cubanes was developed. The precursor molecule, cubane-1,2,4-tricarboxylic acid trimethyl ester, is easily accessible via photolysis with oxalyl chloride. From this, several cubanes of this rarer trisubstituted system were synthesized, including their first examples containing nitro groups.
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