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Andrew Barker

As seen in: Royal Society of Chemistry
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Articles

Spin State Solvomorphism in a Series of Rare S = 1 Manganese(III) Complexes

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By Grace Morgan, Conor Kelly, Irina Alexandra Kuehne, Andrew Barker
| Royal Society of Chemistry Verified
Spin State Solvomorphism in a Series of Rare S = 1 Manganese(III) Complexes Structural, magnetic and spectroscopic data of four complex salts, [Mn(napsal2323)]NTf2, 1,[Mn(napsal2323)]ClO4, 2, [Mn(napsal2323)]BF4, 3 and Mn(napsal2323)]NO3, 4, of the [Mn(napsal2323)]+ complex cation indicate that the Mn3+ ion is stabilized in the rare S = 1 spin triplet form in this ligand sphere.
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Spectroscopic study of the loading of cationic porphyrins by carbon nanohorns as high capacity carriers of photoactive molecules to cells

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By Stephen Devereux, Marina Massaro, David T Hinds, Andrew Barker
| Royal Society of Chemistry Verified
Spectroscopic study of the loading of cationic porphyrins by carbon nanohorns as high capacity carriers of photoactive molecules to cells Carbon nanomaterials are attractive candidates for drug delivery due to their high surface area, ease of functionalisation and biocompatibility. This work describes the spectroscopic monitoring of the loading capacity of oxidised carbon nanohorns for two cationic porphyrins.
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