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Multi-Spectroscopic Determination of Exchange Coupling, Zero-Field Splitting, and g-Matrices in Radical-Bridged Dinuclear Fe(III) Complexes Click to copy article link Article link copied!
Abstract Click to copy section linkSection link copied! When the energy gap, Δ, between the lowest-lying spin manifolds within a spin-exchange coupled molecule approaches Δ/kB ≈ 300 K, the traditional temperature-dependence (T < 400 K) of the molar magnetic susceptibility is not always a reliable way to obtain a good estimate of intramolecular exchange couplings.
Overhauser Dynamic Nuclear Polarization of Lithiated Graphite Anodes: Probing Bulk and Surface Structures
Introduction Click to copy section linkSection link copied! Graphite anodes are the most successful anode materials for lithium-ion batteries (LIBs) to date, (1,2) with high reversible capacities and long lifetimes. Despite their success, graphite anodes are still subject to a series of degradation reactions that occur during battery cycling.
Six-coordinated nickel (II) complexes with benzothiadiazole Schiff-base ligands: synthesis, crystal structure, magnetic and HFEPR study
Six-coordinated nickel (II) complexes with benzothiadiazole Schiff-base ligands: synthesis, crystal structure, magnetic and HFEPR study Two new nickel(II) complexes, namely Ni(L1)2 (1) and Ni(L2)2·CH2Cl2(2) were obtained by reacting nickel (II) acetate tetrahydrate with the benzothiadiazole Schiff base ligands HL1 = 2-[4-(2,1,3-benzothiadiazole)imino]methyl-phenol or HL2 = 2-[(2,1,3-benzothiadiazol-4-ylimino)methyl]-6-methoxyphenol in the presence of Et3N.
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