Arthur Rainer Lit on Muck Rack

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Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acids

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By Shing-Hing Lau, Claudio Bomio, Mikhail A. Kabeshov, Arthur Rainer Lit
| Royal Society of Chemistry Verified
By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon-carbon homologation of aryl and vinyl boroxines using TMSCHN2, giving access to TMS-pinacol boronic ester products, was developed.
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