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Aryaman Pattanik on Muck Rack

Aryaman Pattanik

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Articles

Aza-Büchner–Curtius–Schlotterbeck Reaction Enables Selective Construction of Quaternary Carbon Centers

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By Simon Angerer, Vincent George, Aryaman Pattanik
| Wiley Online Library Verified
1 Introduction Quaternary carbon centers, sp3-carbon atoms bonded to four carbon substituents, are prevalent structural motifs in natural products [1]. Their incorporation into active pharmaceutical ingredients (APIs) and agrochemicals is often associated with enhanced metabolic stability, improved target selectivity, and a desirable increase in three-dimensional molecular complexity [2], in line with the “escape from flatland” paradigm [3-5].
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