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Phosphine–Urea-Supported Nickel Catalyst for Ethylene/Acrylate Copolymerization Click to copy article link Article link copied!
Cite Jump to ExpandCollapse CommunicationApril 23, 2026 Phosphine–Urea-Supported Nickel Catalyst for Ethylene/Acrylate Copolymerization Click to copy article linkArticle link copied! Asim Maity Asim Maity Core R&D, The Dow Chemical Company, Midland, Michigan 48667, United States Todd D. Senecal Todd D. Senecal Core R&D, The Dow Chemical Company, Midland, Michigan 48667, United States Keosha Cade Keosha Cade Core R&D, The Dow Chemical Company, Midland, Michigan 48667, United States Briana S.
Aziridine Group Transfer via Transient N-Aziridinyl Radicals
Aziridines are important synthetic building blocks and represent electrophilic pharmacophores in a variety of organic small molecule therapeutics and natural products (Figure 1a). (1) Aziridines are typically constructed via [2 + 1] cycloadditions between either olefins with nitrene equivalents or imines with carbene equivalents, or via intramolecular nucleophilic substitution chemistry within prefunctionalized substrates (Figure 1b).
Iodanyl Radical Catalysis
Conspectus Hypervalent iodine reagents find application as selective chemical oxidants in a diverse array of oxidative transformations. The utility of these reagents is often ascribed to (1) the proclivity to engage being selective two-electron redox transformations; (2) facile ligand exchange at the three-centered, four-electron (3c–4e) hypervalent iodine–ligand (I–X) bonds; and (3) the hypernucleofugacity of aryl iodides.
Electrocatalytic C-N Coupling via Anodically Generated Hypervalent Iodine Intermediates
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2020, XXXX, XXX RETURN TO ARTICLES ASAPPREVCommunicationNEXT Asim Maity Asim Maity Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States Brandon L. Frey Brandon L. Frey Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States Nathanael D. Hoskinson Nathanael D.
The Role of Iodanyl Radicals as Critical Chain Carriers in Aerobic Hypervalent Iodine Chemistry
Howard J.A. Chapter 12: Homogeneous Liquid Phase Autoxidations. in: Free Radicals. 2. John Wiley & Sons, ; 1973: 3 Walling C. Foote C.S. Valentine J. Greenberg A. Liebmann J.F. Active Oxygen in Chemistry. Blackie Academic-Professional, ; 1995 Lucarini M. Pedulli G.F. Free radical intermediates in the inhibition of the autoxidation reaction. Chem. Soc. Rev. 2010; 39: 2106-2119 Poon J.F. Pratt D.A. Recent insights on hydrogen atom transfer in the inhibition of hydrocarbon autoxidation. Acc. Chem. Res.
Oxidation Catalysis by an Aerobically Generated Dess-Martin Periodinane Analogue
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors.
Oxidation Catalysis by an Aerobically Generated Dess-Martin Periodinane Analogue
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors.
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