Aslan Yu Tsivadze

Non-aggregated ruthenium naphthalocyanine enabling homogeneous carbene insertion into N-H bonds at low catalyst loading The novel ruthenium octa-n-butoxy-naphthalocyanine complex was shown to retain essentially monomeric state in diluted solutions. It was succesfully applied as homogeneous catalyst for the carbene insertion to N-H bonds of amines with various substitution pattern providing high yields of glycine derivatives. This article is Open Access This article has not yet been cited.

ABSTRACT The thermodynamic radii of 15 metal ions Ag+, Al3+, Am3+, Ba2+, Be2+, Fe3+, Ga3+, Hg2+, In3+, K+, Li+, Na+, NpO2+, Sr2+, and UO22+ were calculated by linear free energy relationship modelling using 8269 experimental stability constants (logK) of ML complexes of 42 metal ions (M) and 1990 diverse organic ligands (L) in water.

E. A. Safonova, M. A. Polovkova, A. G. Martynov, Y. G. Gorbunova and A. Y. Tsivadze, Dalton Trans., 2018, Accepted Manuscript , DOI: 10.1039/C8DT03661F If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center. Go to our Instructions for using Copyright Clearance Center page for details.