Avery J To on Muck Rack

Avery J To

As seen in: Wiley Online Library
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Articles

Synthesis and Application of D‐ and 13C‐Labelled tert‐Butyl Hoechst Dye

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By Yulia A. Vlasenko, Avery J To, Tess Fortier, Natasha Evans
| Wiley Online Library
1 Introduction Elucidating the three-dimensional structure and dynamics of biomolecular complexes, such as a nucleic acid–ligand complex, is required for a molecular-level understanding of its function [1-3]. Nuclear magnetic resonance (NMR) spectroscopy can be used to study these complexes; however, there are some limitations. RNA and DNA have a narrower chemical shift distribution in comparison with proteins [4, 5].
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Copper‐Catalyzed α‐Arylation of Sulfoxonium Ylides Using Hypervalent Iodine Compounds

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By Radell Echemendía, Avery J To, Graham Murphy
| Wiley Online Library
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description adsc202301061-sup-0001-misc_information.pdf4.6 MB Supporting Information References 1 1a, , J. Am. Chem. Soc.
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Difluorinative ring expansions of benzo-fused carbocycles and heterocycles are achieved with p-(difluoroiodo)toluene

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By Zhensheng Zhao, Avery J To, Graham Murphy
| Royal Society of Chemistry
Difluorinative ring expansions of benzo-fused carbocycles and heterocycles are achieved with p-(difluoroiodo)toluene† A chemoselective fluorinative ring expansion has been realized using the hypervalent iodine (HVI) reagent p-TolIF2, which delivers β,β-difluoroalkyl arenes in yields up to 89% and allylic gem-difluorides in yields up to 78%. This rapid reaction exploits the ambiphilic nature of alkenes and allenes, and incorporates both fluorine atoms of the (difluoroiodo)arene in the products.
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