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Enantioselective Radical Sulfonylation of 2-Naphthols and β-Ketoamides with Sodium Sulfinates
Cite Jump to ExpandCollapse ArticleNovember 27, 2025 Enantioselective Radical Sulfonylation of 2-Naphthols and β-Ketoamides with Sodium Sulfinates Click to copy article linkArticle link copied! Hongye Li Hongye Li Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China Zhiqiang Li Zhiqiang Li Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu...
Concise synthesis of chiral γ-butenolides via an allylation/lactonization cascade
Concise synthesis of chiral γ-butenolides via an allylation/lactonization cascade A highly enantioselective allylation/lactonization cascade of enone diesters with potassium allyltrifluoroborates was accomplished by a chiral N,N'-dioxide/indium(III) complex. This protocol provided a concise and efficient route to a number of enantioenriched γ-butenolides under mild conditions. Most of examples completed within 10 minutes with high enantioselectivity.
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