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Efficient Alkene Hydroformylation by Co-C Symmetry-Breaking Sites
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2024, XXXX, XXX Terms & Conditions Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses).
Achieving rhodium-like activity for olefin hydroformylation by electronic metal-support interaction of single atomic cobalt catalyst
Catalytic performance for olefin hydroformylation We applied the established atomic-scale Co-based catalysts in the hydroformylation of propene to evaluate their catalytic activity. Firstly, the relationship between Co loading and hydroformylation performance (TON and TOF) were studied (Figure 3A ). At high Co loading, e.g., 5% or higher, the TON was relatively low. For example, the TON for the Co(10%)/β-Mo2C catalyst was only 443.
Regioselective Hydroxymethylation of Alkenes to Linear Alcohols with CO2/H2 Using a Rh/Ru Dual Catalyst
CO2 is an attractive renewable C1 resource, and H2 is a cheap and green reductant. The combination of CO2 and H2 for hydroxymethylation of alkenes provides a novel synthetic tool to directly generate alcohols, especially linear ones, which are generally preferred as precursors of detergents and plasticizers.
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