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A strategy For High Ethylene Polymerization Performance Using Titanium Single-Site Catalysts
The synthesis of heterogeneous Ti(IV) based catalysts for ethylene polymerization following Surface Organometallic Chemistry concepts is described. The unique feature of this catalyst arises from the silica support, KCC-1700. It has (i) a 3D fibrous morphology that is essential to improve the diffusion of the reactants, (ii) an aluminum-bound hydroxyl group, [(≡Si-O-Si≡)(≡Si-O-)2Al-OH] 2, used as an anchoring site.
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