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Barbara Daffos on Muck Rack

Barbara Daffos

As seen in: Wiley Online Library, Royal Society of Chemistry, Chemistry World
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Articles

Polymerization of EDOT functionalized star-shaped pentaerythritol and study of the structure and conducting properties of polymers

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By Barbara Daffos, Pierre-Louis Taberna, Charles Cougnon, Rana Abdel Samad
| Royal Society of Chemistry Verified
Polymerization of EDOT functionalized star-shaped pentaerythritol and study of the structure and conducting properties of polymers Conducting polymers (CPs) are undergoing a renewal in light of new challenges in energy storage posed by the environmental crisis through expanding their application to concepts of conducting redox polymers, nanostructured CPs and porous CPs. But if their conducting properties are widely documented, the same cannot be said for their structural properties, causing...
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Thermal Oxidation of Carbonaceous Nanomaterials Revisited: Evidence of Mechanism Changes

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By Emmanuel Picheau, Ferdinand Hof, Alain Derré, Barbara Daffos
| Wiley Online Library Verified
Cover Picture Dr. Alain Pénicaud Corresponding Author E-mail address: alain.penicaud@crpp.cnrs.fr http://orcid.org/0000-0001-8614-2867 Centre de Recherche Paul Pascal, CRPP UMR5031-CNRS/, Université de Bordeaux, 115 Avenue du Dr Albert Schweitzer, 33600 Pessac, France Search for more papers by this author PDF PDF Share Abstract Despite 450 000 years of human use, carbon combustion still holds secrets. In their Communication (DOI: 10.1002/anie.201906026), A. Pénicaud et al.
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Improved electro-grafting of nitropyrene onto onion-like carbon via in situ electrochemical reduction and polymerization: tailoring redox energy density of the supercapacitor positive electrode - Journal of Materials Chemistry A (RSC Publishing)

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By Bihag Anothumakkool, Pierre-Louis Taberna, Université Paul Sabatier, Barbara Daffos
| Chemistry World Verified
Herein, we report an improved method for the physical grafting of 1-nitropyrene (Pyr-NO ) onto highly graphitized carbon onion. This is achieved through a lowering of the onset potential of the pyrene polymerization via in situ reduction of the NO group. The additional redox activity pertaining to the reduced NO enables exceeding the faradaic capacity, which is associated with the p-doping of the grafted pyrene backbone, as observed for pyrene, 1-aminopyrene, and unreduced Pyr-NO .
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