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Enhancing Selectivity of La─Ce─O Catalyst in Oxidative Coupling of Methane by Na2WO4 Doping
Conflict of Interests The authors declare no conflict of interest. References 1, , , , , , , Carbon Resour. Convers. 2022, 5, 1–14. 2, , , , Handbook of Heterogeneous Catalysis Wiley-VCH, Weinheim, 2008, 6, pp. 3010–3023. 3, , , , Ceram. Int. 2023, 49, 1902–1910. 4, , , , , , , Appl. Surf. Sci. 2021, 553, 149554. 5, , , , , , , Mater. Today Sustain. 2025, 29, 101053. 6, , , , , , Appl. Catal., A: Gen. 2012, 53, 425–426. 7, , , , , , J. Catal. 2022, 408, 423–435. 8, , , , , , , J. Energy Chem. 2021, 60, 649–659.
High-performance Cr-Zr-O and Cr-Zr-K-O catalysts prepared by nanocasting for dehydrogenation of propane to propene
Ordered mesoporous Cr-Zr-O and Cr-Zr-K-O catalysts were prepared by nanocasting using CMK-3 carbon replica as a hard template. The synthesized oxide nanoreplicas had a uniform pore-size distribution centered in the range of 5.5-6.5 nm and specific surface areas of 123-164 m2/g. Results of physicochemical characterization (UV-Vis DRS, EPR, XRD, XPS and H2-TPR) revealed that chromium species were stabilized at +3, +5 and +6 oxidation states in all samples.
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