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N2 Functionalization via Molybdenum‐Nitride Complex: Stepwise BH Bond Additions
Introduction The transformation of atmospheric N2 into NH3 is one of the most important reactions to mankind. It is done by Nature on huge scales (ca 210 million tons N fixed as NH3 per year),1 by nitrogen fixing bacteria which possess nitrogenase enzymes.
Ammonia Synthesis at Room Temperature and Atmospheric Pressure from N2: A Boron‐Radical Approach
Graphical Abstract Boron-centered radicals, generated by reduction of R2BCl derivatives, react with N2 all the way to borylamine formation. DFT calculations rationalize the reduction/functionalization process, involving N−N bond splitting. Hydrolysis of the mixture yields NH4+. Radical addition to N2 provides a new strategy for N2 fixation. Abstract Ammonia, NH3, is an essential molecule, being part of fertilizers.
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