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Cluster Anions of Hydrated Polycyclic Aromatic Hydrocarbons: “Magic” Water Tetramer Click to copy article link Article link copied!
Introduction Click to copy section linkSection link copied! The water monomer cannot form a stable bound anion. A quasibound gas-phase H2O– was detected, (1) but it is unstable in geometries close to the equilibrium structure of the water molecule. (2,3) Aggregated water molecules can cooperatively support a bound state for excess electrons, and negatively charged water clusters have been observed in many experiments.
Hydrated Formic Acid Clusters and their Interaction with Electrons
Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
Electron-triggered processes in halogenated carboxylates: Dissociation pathways in CF3COCl and its clusters
Electron-triggered processes in halogenated carboxylates: Dissociation pathways in CF3COCl and its clusters Trifluoroacetyl chloride, CF3COCl, is produced in the Earth’s atmosphere by photooxidative degradation of hydrochlorofluorocarbons, and represents a potential source of highly reactive halogen radicals. Despite considerable insight obtained into photochemistry of CF3COCl, its reactivity towards electrons has not been addressed so far.
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